Research

Dec 20th, 2015
Metal nanowire films as transparent conducting oxide replacement and plasmonic

Nanowires formed at the solution-substrate interface using the Markovich technique could be used as a semi-conductive layer in PV cells as well as in various other applications.

  • Solar
  • Solar

The Markovich Group is working on a transparent electrode for photovoltaic (PV) cells employing a technique they developed themselves for preparing ultra-thin gold/silver nanowire mesh films using a simple self-assembly process.

The uniqueness of this process lies in the in-situ deposit of the nanowires while their precursors are self-assembling on the surface. This as compared to other competing techniques which are based on the spreading of prefabricated metal nanorods or carbon nanotubes on graphene sheets.

With the Markovich technique the nanowires are formed at the solution-substrate interface, establishing sound electrical contact with the substrate and could thus be used as one of the PV cell’s semi-conductive layers. The team is currently exploring, in addition to PV cells, a number of other applications requiring transparent conductors.

Such nanowires could also be used for the plasmonic enhancement of light absorption on the surfaces of species such as molecules, polymers and semiconductor nanoparticles.

The Markovich Group is also engaged in a separate study for the plasmonic enhancement of light absorption in various biological molecular systems such as photosynthetic proteins.

The Group has already demonstrated a 100 fold absorption enhancement in model molecules using silver nanoparticles.

 

 

 

 

Research

Dec 20th, 2015
Distributed solar cogeneration

Concentrating Photovoltaic (CPV) systems can produce both heat and electrical power from solar radiation, at a combined efficiency exceeding 70%.

  • Solar
  • Solar

Concentrating Photovoltaic (CPV) systems produce large amounts of waste heat in addition to electricity. This heat could be collected and delivered as an additional and valuable energy product (cogeneration). It could be used for water or space heating, for steam or process heat for industry, or converted to air conditioning using an absorption chiller. The overall efficiency of such a cogeneration plant could be more than 70% (compared to up to 25% when using only the electricity), and the value of the energy to the end user in this cogeneration mode could be approximately double that of the electricity alone. We have developed this concept and analysed its thermodynamic performance, and also its cost effectiveness. We have shown that using cogenerated heat for air conditioning leads to the lowest cost option for solar air conditioning. When using the heat for thermal desalination of seawater, the cost of the water could be lower than desalinating with reverse osmosis, and in some cases the desalinated water could actually cost nothing. We have also developed a technical demonstration of a small cogeneration CPV unit, designed for urban rooftops, providing distributed cogeneration to larger buildings with suitable rooftops.

 

Collaboration with partners from Italy, Germany and Spain

Support: European Commission, FP6

Research

Dec 20th, 2015
Solar thermionic converter

Thermionic conversion of concentrated solar radiation at 800-1000°C, using innovative materials and heat recovery, can generate electricity and heat at high overall efficiencies.

  • Solar
  • Solar

Thermionic conversion of concentrated solar radiation at 800-1000°C, using innovative materials and heat recovery, can generate electricity and heat at high overall efficiencies.

Thermionic conversion uses high temperature thermal energy to drive electrons across a gap and thus creating an electrical current. A thermionic converter is a solid state device with no moving parts, with the main challenge being the high temperatures. We are developing a converter, based on advanced ceramic materials and surface coatings, that allows efficient electron emissions at temperatures below 1000°C (typically thermionic devices operate well above 1000°C). The thermionic emitter also serves as an absorber of concentrated solar radiation to provide heating. The thermionic converter is coupled to a second stage thermo-electric converter that uses ‘waste’ heat from the thermionic stage to produce additional electricity. The overall efficiency of this 2-stage design is expected to be around 35%. It is also possible to collect the low-grade heat rejected from the bottom of the thermo-electric converter at about 90°C and use it as an additional energy product in cogeneration mode. In this project we are developing the basic materials, coatings and processes necessary to create an efficient thermionic converter, constructing a demonstration device with both thermionic and thermo-electric stages, and testing the device in a solar furnace to validate its operation.

 

Collaboration with partners from Italy and Turkey

Support: European Commission, FP7

Research

Dec 20th, 2015
Thermal storage for solar steam power plants

An innovative heat transfer method for thermal storage in solar thermal power plants based on a steam cycle, will allow long-term operation at high efficiencies.

  • Solar
  • Solar

Solar thermal power plants are able to continue operating through periods of cloud cover and into the night, provided that extra solar heat is stored during sunny periods and can be extracted when needed. For power plants based on the steam Rankine cycle, most of the heat is needed at a constant temperature of around 300°C, which ideally matches the storage temperature of the Phase Change Materials (PCM). Unfortunately due to their low thermal conductivity, suitable PCMs do not allow easy input and extraction of the heat, and this barrier prevents efficient charging and discharging of the storage material. We are developing an innovative method of heat transfer that will overcome this bottleneck, enabling fast transfer of heat into and out of the storage material while at the same time minimising temperature changes and keeping the process at nearly constant temperature (isothermal). This will allow the power plant to maintain constant high efficiencies when operating from storage. We are analysing the proposed process in order to validate its principles, and we’re constructing a detailed simulation for predicting its performance. Following this validation, an experimental model will be built to demonstrate and measure actual performance.

 

Collaboration: M. Rosenfeld (TAU)

 

Research

Dec 20th, 2015
Solar Energy for Water Disinfection

Large quantities of drinking water can be disinfected quickly and cheaply by combining solar heating and ultra-violet irradiation

  • Solar
  • Solar

Contaminated drinking water is one of the main causes of disease and mortality in developing countries. Former Porter Fellow Dr Hadas Mamane, in collaboration with Professor Kribus, is developing a method for disinfecting large amounts of water using solar energy. This exciting new research has the potential of improving the health and quality of life for people in poor communities in third world countries who have little or no access to clean drinking water, and cannot afford modern water treatment technologies.

The ultra-violet (UV) part of solar radiation is known for its ability to disinfect water by destroying or inactivating microbial cells, but solar UV by itself is a very weak disinfectant. Disinfection by solar heating can be effective but requires high temperatures. A combination of both heat and UV can produce higher rates of disinfection than the sum of the two processes operating separately. However, the solar disinfection technology presently available, known as SODIS (solar water disinfection), can treat only small amounts of water at a time, and requires a long time of exposure to solar radiation (typically 6 hours or more).

 

A recent exciting discovery in Mamane and Kribus’ research is that certain additives can accelerate the disinfection process, reducing the time and lowering the needed temperature. These additives are abundant, inexpensive, and safe materials. The use of these additives, together with knowledge obtained in ongoing studies of the various process parameters, will enable the definition of optimum low-cost but highly effective solar disinfection technology. These advances in solar disinfection can be used in small scale (similar to SODIS) or in large community-scale water treatment systems.

The technology developed by Mamane and Kribus involves what Mamane calls a “synergy” of heat, solar radiation and a natural water additive. “The idea,” explains Mamane, “is to find a method of disinfecting water that is cheap and that takes advantage of the natural properties of solar heating.”

She adds, “Developing countries don’t have much money – but they do have sunlight!”

Research

Dec 20th, 2015
Artificial Leaf to Collect Solar Energy from Sun.

Power Plants” Based on Bacteria Could Be Cheaper Than Today’s Solar Energy Technology        

  • Solar
  • Solar

 

“Power Plants” Based on Bacteria Could Be Cheaper Than Today’s Solar Energy Technology        

In evolutionary terms, plants and bacteria are the earliest solar energy generators on the planet, refining the process over billions of years. Acknowledging the wisdom of Mother Nature, Tel Aviv University scientists have discovered a way to connect the energy produced by bacteria’s photosynthetic proteins to electrodes, thereby creating a novel form of solar energy –– both abundant and cheap.

On its own, nature creates for us materials that collect the sun's energy, and all we need to do is extract them from the bacteria and use them. These materials do exactly the same thing as silicon-based photovoltaic cells - they collect sunlight and create an electrical charge.

 

“Power Plants” of the Future

A multidisciplinary research super-team led by Prof. Chanoch Carmeli fromLife Sciences, Dr. Shachar Richter and Dr. Itai Carmeli (the principle inventor) from Exact Sciences and Prof. Yossi Rosenwaks from Electrical Engineering, have put their minds together and developed a way to convert the power produced by the PS I proteins from bacteria into electricity we can use. 

The team introduced genetic changes into bacteria so that the proteins they create can bond to a substrate bottom metal and be suited for use. Collecting a single photosynthetic protein from the bacteria, the scientists modified the protein so that they could arrange them in layers in a dry state  and place the protein concentrate between two electrodes.  The scientists then connected electrical wires to the protein cells, which produce an electrical charge when exposed to light.

The finding of this novelphotovoltaic cell in effect artificial leaves or “power plants” that harness photosynthetic energy was announced at Tel Aviv University’s Renewable Energy and Beyond in May, the largest renewable energy conference to take place in Israel; and where Al Gore was an honoured guest.

This novel solution, which creates artificial leaves using bacteria proteins are a fraction of the cost of the silicon used in solar energy collectors today.  Today’s photovoltaic cells made from silicon can convert solar energy to electricity, but due to the extremely high price of silicon, it costs four times more to generate power from solar energy than by using coal or petroleum.  This inter-disciplinary project weaves together both mature and young cutting-edge knowledge from engineering, electronics, nano-technology, chemistry and biology. Feasibility studies have been proven and the University’s technology transfer arm Ramot is set to commercialize

Research

Dec 20th, 2015
High-voltage photovoltaic cells

PV cells can achieve higher efficiencies under concentrated sunlight with vertical multi-junction structure, producing high voltage and low current.

  • Solar
  • Solar

The common structure of PV cells produces low voltage and high current. This leads to high losses due both to current mismatch when cells are connected together in panels, and to electrical resistance, especially in concentrator systems where currents are high. The Vertical Multi-Junction (VMJ) approach on the other hand produces cells with high voltage and low current, thereby reducing electrical resistance losses (which depend on the current), and enabling a different configuration for connecting the cells (parallel instead of series) that minimises mismatch effects. We have shown that a VMJ cell in silicon can achieve significantly higher efficiencies than those previously demonstrated (close to 30%, compared to around 20% in previous work). The essential difference lies in the  design of the basic unit in the cell, the single junction, which needs to be much narrower than in previous designs in order to achieve optimal conversion efficiency. The optimised VMJ cells also operate efficiently at much higher concentrations than conventional cells made from the same material, for example at more than 1000 suns for silicon cells, while the performance of conventional silicon cells degrades at concentrations exceeding about 300. We are currently investigating different cell structure options, together with corresponding methods of cell manufacture, to find designs that would be both inexpensive and practical.

 

Collaboration: R Sarfaty (OBC)

Support: Israel Ministry of National Infrastructure

Research

Dec 20th, 2015
Photon Enhanced Thermionic Emission (PETE) converters

Advanced modelling and experimental validation is required for improving and optimising the performance of the PETE converter. This would result in a dramatical increase in energy conversion efficiencies in combined cycles with a heat engine.

  • Solar
  • Solar

PETE is a new and exciting concept in solar energy research. In standard photovoltaic applications only the semiconductor band gap can be considered as ‘useful voltage’, in PETE converters a thermal boost (due to the use of concentrated radiation) allows higher operating voltages to provide higher conversion efficiencies. In addition, under conditions of high photon flux, the energy barrier for electron emission is lowered, enabling efficient energy conversion at moderate temperatures that are typically insufficient for ordinary thermionic emission converters.

PETE is a relatively new and poorly understood concept. The only PETE model reported to date  does not take into account important aspects such as bulk and surface recombination in the semiconductor, spatial variations of charge carrier concentrations and temperature and many more. Hence, an elaborate model is under development in order to determine the PETE conversion efficiency upper limit. An understanding of these issues is essential for the optimal design of a PETE based converter that will achieve the highest conversion efficiencies possible. Additional effects are under consideration for increasing the conversion efficiency, such as decoupling of the absorber and emitter areas – shown to improve efficiency in thermophotovoltaic (TPV) and thermophotonic (TPX) devices; the application of an external bias field, or the creation of an internal field using a heterojunction; enhancing locally the field at the cathode to enhance electron emission by surface nanostructures. Investigating this wealth of phenomena and potential enhancements is underway using advanced modeling as well as experimental validation.

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